In 1930, when Herbert Becker and Walter Bothe sent Alfa particles against beryllium, strong penetrating radiation was emitted, there was a hypothesis that this could be electromagnetic radiation of high energy.
In 1932, it was James Chadwick that would show in the reaction, a neutral particle with the mass of a proton was emitted.
Projected Alfa particles (two protons and two neutrons bound together) and when the Alfa particles reached the beryllium (a chemical element with the atomic number 4) the beryllium became neutrons and fell off on paraffin wax.